
22' diameter ammonium sulfate crystallizer
designed for Shell Chemical Company to produce 600 tons
of (NH4)2SO4
per day
SWENSON two-stage
forced-circulation evaporative crystallizer at Armour
Agricultural Chemical Company
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Crystallization:
An industrial process for producing high-purity compounds
from impure solutions with low energy input.
Crystallization is the
process by which a chemical is separated from solution as
a high-purity, definitively shaped solid.
A crystal may be defined as a
solid composed of atoms arranged in an orderly,
repetitive array. The inter-atomic distances in a crystal
of any definite material are constant and characteristic
of that material. Crystals are, in short, high-purity
products with consistent shape and size, good appearance,
high-bulk density and good handling
characteristics.
Because the pattern or
arrangement of the atoms is repeated in all directions,
there are definite limitations on the shapes which
crystals may assume. For each chemical compound, there
are unique physical properties differentiating that
material from others, so the formation of a crystalline
material from its solution, or mother liquor, is
accompanied by unique growth and nucleation
characteristics.
While crystallization is a unit
operation embracing well known concepts of heat and mass
transfer, it is nevertheless strongly influenced by the
individual characteristics of each material handled.
Therefore, each crystallization plant requires many
unique features based upon well established general
principles. Each application must be evaluated on an
individual basis to achieve optimum results.
The mechanical design of the
crystallizer has a significant influence on the
nucleation rate due to contact nucleation (that which is
caused by contact of the crystals with each other and
with the pump impeller, or propeller, when suspended in a
supersaturated solution). This phenomenon yields varying
rates of nucleation in scale up, and differences in the
nucleation rates when the same equipment is used with
different materials.
It is important in performing pilot plant tests that designs are
used in which both the small- and large-scale
characteristics are well known, and that the testing is
performed by highly experienced personnel.
Swenson Crystallization experience
The Swenson Evaporator
Company, was formed in 1889 to build
sugar evaporation and crystallization equipment. Since
that time, Swenson has become a recognized force in the
market and has broadened its capabilities to include the
manufacture of a wide range of crystallization equipment,
including evaporative, surface-, vacuum- and
refiigerant-cooled crystallizers ranging in size from
pilot plant equipment to units over 40' in
diameter.
Swenson has long
maintained a fully staffed, fully equipped laboratory for development and
feasibility testing. The facilities include a rising film
and falling
film evaporator, a forced-circulation evaporative
crystallizer, two draft tube baffle crystallizers,
and a small glass unit capable of handling about three
liters of slurry. Operation is typically "around the
clock" and tests with centrifuges, filters and
dryers can be made so that the laboratory product will
resemble the
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